Tuesday 5 January 2010

Glass




A glass is an amorphous (non-crystalline) solid material. Glasses are typically brittle, and often optically transparent. Glass is commonly used for windows, bottles, or eyewear and examples of glassy materials include soda-lime glass, borosilicate glass, acrylic glass, sugar glass, Muscovy-glass, or aluminium oxynitride.

The term glass developed in the late Roman Empire. It was in the Roman glassmaking center at Trier, now in modern Germany, that the late-Latin term glesum originated, probably from a Germanic word for a transparent, lustrous substance.
Strictly speaking, a glass is defined as an inorganic product of fusion which has been cooled through its glass transition to the solid state without crystallising.Many glasses contain silica as their main component and glass former.

The term "glass" is, however, often extended to all amorphous solids (and melts that easily form amorphous solids), including plastics, resins, or other silica-free amorphous solids. In addition, besides traditional melting techniques, any other means of preparation are considered, such as ion implantation, and the sol-gel method.


Commonly, glass science and physics deal only with inorganic amorphous solids, while plastics and similar organics are covered by polymer science, biology and further scientific disciplines.
Glass plays an essential role in science and industry.

The optical and physical properties of glass make it suitable for applications such as flat glass, container glass, optics and optoelectronics material, laboratory equipment, thermal insulator (glass wool), reinforcement fiber (glass-reinforced plastic, glass fiber reinforced concrete), and art.


Glass ingredients


Pure silica (SiO2) has a "glass melting point"— at a viscosity of 10 Pa·s (100 P)— of over 2300 °C (4200 °F).

While pure silica can be made into glass for special applications (see fused quartz), other substances are added to common glass to simplify processing. One is sodium carbonate (Na2CO3), which lowers the melting point to about 1500 °C (2700 °F) in soda-lime glass; "soda" refers to the original source of sodium carbonate in the soda ash obtained from certain plants. However, the soda makes the glass water soluble, which is usually undesirable, so lime (calcium oxide (CaO), generally obtained from limestone), some magnesium oxide (MgO) and aluminium oxide (Al2O3) are added to provide for a better chemical durability.

The resulting glass contains about 70 to 74% silica by weight and is called a soda-lime glass.Soda-lime glasses account for about 90% of manufactured glass.


As well as soda and lime, most common glass has other ingredients added to change its properties. Lead glass, such as lead crystal or flint glass, is more 'brilliant' because the increased refractive index causes noticeably more "sparkles", while boron may be added to change the thermal and electrical properties, as in Pyrex.

Adding barium also increases the refractive index. Thorium oxide gives glass a high refractive index and low dispersion, and was formerly used in producing high-quality lenses, but due to its radioactivity has been replaced by lanthanum oxide in modern eye glasses.

Large amounts of iron are used in glass that absorbs infrared energy, such as heat absorbing filters for movie projectors, while cerium(IV) oxide can be used for glass that absorbs UV wavelengths (biologically damaging ionizing radiation).
Two other common glass ingredients are calumite (an iron industry by-product) and "cullet" (recycled glass).

The recycled glass saves on raw materials and energy.

However, impurities in the cullet can lead to product and equipment failure.
Finally, fining agents such as sodium sulfate, sodium chloride, or antimony oxide are added to reduce the bubble content in the glass.Glass batch calculation is the method by which the correct raw material mixture is determined to achieve the desired glass composition

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